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The disproportionation of O 2 by manganese porphyrin is based on the conversion between Mn III and Mn II accompanied by outer-sphere proton-coupled one-electron transfer 27 , and the redox potential of metal center is a dominating factor for enabling the reaction in accordance with the Marcus equation 28

After all, radiation exposure exponentiates free radical activity, and paradoxically, has led to partial reversals in graying