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The Master Antioxidant Explained offers a useful overview

The question of whether a serum "works topically" is largely a function of whether its molecules ever cross the skin barrier

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Though still being studied, it has gained attention in functional medicine and biohacking circles for its powerful regenerative, anti-inflammatory, and performance-enhancing properties

Under normal conditions, the antioxidant defence systems are probably capable of maintaining a low steady-state level of damage and thus protecting the cells (Zhou et al.2003)