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In overdose the glutathione mechanism is overwhelmed

Molecules 26(16):5001 Kumar A, Yegla B, Foster TC (2018) Redox signaling in neurotransmission and cognition during aging

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While milk thistle doesn't provide the "master antioxidant" directly, it acts as a precursor or a biological catalyst

Nutr Hosp 21(6):704708 Schauer A, Knauer H, Ruckenstuhl C, Fussi H, Durchschlag M, Potocnik U, Frhlich KU (2009) Vacuolar functions determine the mode of cell death

It is added illegally to food to extend its shelf life due to its antiseptic and preservation properties [45] (Fig