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The oxidation of compound with t-BuOOH produces the transient selenoxide , which undergoes a spontaneous cyclization to produce the dioxyselenurane isolated compound structure was confirmed by spectroscopic methods and single X-ray crystallography

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Food Chem 134:141148 Hitchcock JK, Mkwanazi N, Barnett C, Graham LM, Katz AA, Hunter R, Schfer G, Kaschula CH (2021) The garlic compound Z-ajoene, S-thiolates COX2 and STAT3 and dampens the inflammatory response in RAW264.7 macrophages