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Once the process is 'overidden' the person is more stable

doi: 10.1210/jc.2005-0628 18 CalcaterraVVerduciECenaHMagenesVCTodiscoCFTenutaEet al

The TPP labelling of PrSH is stable, while that of PrSS and PrS(S) n S is via a disulfide and is consequently lost upon reduction and further alkylation with IAM, in agreement with Fig