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This is because muscle tissue has a greater blood supply than the tissue just under your skin

Fischer, J

Anti-Interleukin-9 Antibody Increases the Effect of Allergen-Specific Immunotherapy in Murine Allergic Rhinitis

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Experimentally, BSO has been widely used to induce GSH depletion (hence increase redox potential +30mV at 100M BSO for 24hrs in HeLa cells [37]) due to its inhibitory effects on GCS production, the rate limiting enzyme in GSH synthesis [38]