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Chiral Pool Synthesis Starting from naturally occurring chiral compounds allows for controlled stereochemistry

I believe that is because of the high absorption and the long half-life

Lombardi, V., Carassiti, D., Giovannoni, G

A., Pharmacokinetics, Pharmacodynamics and Tolerability of Multiple Oral Doses of Linagliptin, a Dipeptidyl Peptidase4 Inhibitor in Male Type 2 Diabetes Patients, Diabetes, Obesity and Metabolism 11, no

These cells function as presynaptic cells that form conventional neuronal synapses with sensory afferent nerve fibers, releasing serotonin, norepinephrine, and GABA as neurotransmitters (51, 52)