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In animal models (rats), its effects on the nitric oxide (NO) pathway through modulation of NO synthase (eNOS) expression have been described

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It is harmless even in huge amounts: Ever since B12 was isolated as a substance, it has been used in extremely high doses to treat cyanide poisoning and a range of illnesses

doi:10.1007/s00592-018-1240-x

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The critical limitation for both compounds is the same: evidence is preclinical, human clinical data is either minimal (BPC-157) or nonexistent (KPV), and both are sourced through unregulated markets where product quality cannot be guaranteed